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yttrium orthovanadate : ウィキペディア英語版
yttrium orthovanadate
Yttrium orthovanadate (YVO4) is a transparent crystal. Undoped YVO4 is also used to make efficient high-power polarizing prisms similar to Glan–Taylor prisms.
There are two principal applications for doped Yttrium orthovanadate:
*Doped with neodymium it forms Nd:YVO4, an active laser medium used in diode-pumped solid-state lasers.
*Doped with europium it forms Eu:YVO4, the dominant red phosphor used in cathode ray tubes especially in color TVs.
==Basic properties==

*Crystal structure:〔
*
*Zircon tetragonal (tetragonal bipyramidal)
*
* Space group D4h
*
* Lattice parameters ''a'' = ''b'' = 7.119 Å, ''c'' = 6.290 Å
*Density: 4.24 g/cm3
*Melting point: 1810–1940 °C 〔
*Mohs hardness: glass-like, ~5
*Knoop hardness: 480 kg/mm2
*Thermal expansion coefficient:〔(【引用サイトリンク】title=Yttrium Vanadate (YVO4) Crystal )
*
* αa = 4.43×10−6/K
*
* αc = 11.37×10−6/K
*Thermal conductivity coefficient:〔
*
*parallel to ''c''-axis: 5.23 W·m−1·K−1
*
*perpendicular to ''c''-axis: 5.10 W·m−1·K−1
*Refractive indices, birefringence ( Δ''n'' = ''n''e - ''n''o) and walk-off angle at 45° (ρ):
*
*at 0.63 µm:
*
*
*''n''e = 2.2154
*
*
*''n''o = 1.9929
*
*
*Δ''n'' = 0.2225
*
*
*''ρ'' = 6.04
*
*at 1.30 µm:
*
*
*''n''e = 2.1554
*
*
*''n''o = 1.9500
*
*
*Δ''n'' = 0.2054
*
*
*''ρ''= 5.72
*
*at 1.55 µm:
*
*
*''n''e = 2.1486
*
*
*''n''o = 1.9447
*
*
*Δ''n'' = 0.2039
*
*
*''ρ'' = 5.69
*
*Sellmeier equation (''λ'' in µm):
*
*
*''n''e2=4.59905 + 0.110534/(λ2 − 0.04813) − 0.012267612 ''λ''2
*
*
*''n''o2=3.77834 + 0.069736/(λ2 − 0.04724) − 0.0108133 ''λ''2

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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